Solar Hydrogen Generation Exceeding 100 Efficiency

Quantum dots are extremely small semiconductor particles only a few nanometers in size.
Solar hydrogen generation exceeding 100 efficiency. Here we report on photocurrent enhancement arising from meg in lead selenide pbse qd based solar cells as manifested by an external quantum efficiency the. We developed a lead sulfide pbs qd photoelectrochemical cell that is able to drive hydrogen evolution from aqueous na 2 s solution with a peak external quantum efficiency exceeding 100. It is generally expected that the rate of hydrogen generation at the cathode or photocathode is twice the rate of oxygen generation at the anodic or photoanode i e the faradaic efficiency of the overall process is 100. What about silicon 1 1 ev.
Exceeding 100 efficiency multiple exciton generation in which two electron hole pairs are generated from the absorption of one high energy. The operating temperature of the pv modules was also an important factor studied in this research to increase efficiency. The optimized pv electrolysis system increased the hydrogen generation efficiency to 12 4 for a solar powered pv pem electrolyzer that could supply enough hydrogen to operate a fuel cell vehicle. For a photo active materials which has band gab of 1 6 ev can exhibit theoretical calculation solar to hydrogen conversion efficiency about 30.
Now a photoelectrochemical system using pbs quantum dots is shown to drive hydrogen evolution with external quantum efficiency over 100. Essentially they created what is known as a quantum dot photoelectrochemical cell that catalytically achieved quantum efficiency for hydrogen gas production exceeding 100 in the case of their experiments an efficiency approaching 114. Download citation solar hydrogen generation. Multiple exciton generation in which two electron hole pairs are generated from the absorption of one high energy photon has been demonstrated to improve efficiency in quantum dot based solar cells.
Qd photoelectrodes that were measured all demonstrated meg when the incident photon energy was larger than 2 7 times the bandgap energy.